1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER	
Supplier:	MELBOURNE CLEANING SUPPLIES
	.3 CATO STREET  
	HAWTHORN EAST VIC 3123
	PH: 03 9880 7333 FAX: 03 98807344
ACN:	057 283 959
	
Emergency telephone number: National Poisons Information Centre: Phone Australia 13 11 26.

Product Name: SUPER BOWL 
Synonym: 

Use:  Acid cleaner/sanitiser for toilet bowls and urinals. Apply undiluted to bowls, scrub with sanitary brush, then flush.

2. HAZARDS IDENTIFICATION	
 NON-HAZARDOUS ACCORDING TO EU CRITERIA

Hazard Category:  Non hazardous

Hazard Classification:  Not applicable

RISK PHRASES 
None allocated
SAFETY PHRASES 
S1/2 Keep locked up and out of reach of children. 
S7/9 Keep container tightly closed and in a well ventilated place. 
S25 Avoid contact with eyes. 
S26 In case of contact with eyes, rinse immediately with plenty of water and contact a doctor or Poisons Information Centre. 
S36/37/39 Wear suitable protective clothing and gloves and eye.  
S45 In case of accident or if you feel unwell, contact a doctor or Poisons Information Centre immediately and show this container or label.

Poison Schedule:  S5 [Aust]
This material is a Scheduled S5 Poison and must be stored, handled and used according to the appropriate regulations..

Warning Statement:
Corrosive.

3. COMPOSITION / INFORMATION ON INGREDIENTS	
SUBSTANCE NAME	Proportion	CAS Number

PHOSPHORIC ACID 	10 to 30%	7664-38-2
HEXADECYLTRIMETHYL AMMONIUM CHLORIDE                 1 to 10%                112-02-7     
WATER AND OTHER NON-HAZARDOUS SUBSTANCES	Greater than 60%	Mixture

This product contains:
                                        Phosphoric Acid       127.5g/LT

All other ingredients not hazardous according to EU Criteria.

4. FIRST AID MEASURES	
Swallowed: 
If swallowed, DO NOT induce vomiting. Give plenty of water to drink. Seek urgent medical assistance.

Eye: 
If material is splashed into eyes, flush with plenty of water for at least 15 minutes, ensuring eye lids are held open. URGENTLY transport to hospital or doctor.

Skin: 
If material is splashed onto the skin, remove any contaminated clothing and wash skin thoroughly with water and soap. Immediately transport to hospital or doctor.

Inhaled: 
Remove victim to fresh air. Do not use mouth-to-mouth method if victim inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.

First Aid Facilities:
Eye wash fountain, safety shower and normal wash room facilities.

Advice to Doctor:
Treat symptomatically.
In case of poisoning, contact Poisons Information Centre
In Australia call Tel: 131126
In New Zealand Tel: 034747000

5. FIRE-FIGHTING MEASURES	
Fire/Explosion Hazard
CAUTION: Use of water spray when fighting fire may be inefficient.
EXTINGUISHING MEDIA:  Use dry chemical, carbon dioxide, foam or water fog.
SPECIAL FIRE FIGHTING PROCEDURES:  Self-contained breathing apparatus (SCBA) required for fire-fighting personnel. If possible to do so safely, shut off fuel to fire. Use water spray to spray to cool fire-exposed surfaces and to protect personnel. 
UNUSUAL FIRE AND EXPLOSION HAZARDS: If tanks, drums or containers of this material are heated, they may rupture and project corrosive liquids over a wide area.

HAZCHEM CODE:  None

FLAMMABILITY
Not flammable or combustible. If involved in a fire may generate noxious and corrosive fumes.

6. ACCIDENTAL RELEASE MEASURES	
EMERGENCY ACTION:
Keep unnecessary people away; Isolate hazard area and deny entry. Stay upwind; Keep out of low areas. Wear appropriate eye, skin and respiratory protection as outlined in this MSDS.
SPILL OR LEAK PROCEDURE:
Shut off ignition sources, no flares, smoking or flames in hazard area. Stop leak if you can do it without risk. Water spray may reduce vapour.
SMALL SPILLS: 
Take up with sand, dirt or vermiculite. DO NOT use sawdust. Use non-sparking tools. Place into labelled drum(s) for later disposal. 
LARGE SPILLS: 
Notify Emergency Services (Police or Fire Brigade). Tell them exact location, nature, hazards, quantities, type of vehicle and any other information that would be helpful. Contain spill. Remove all ignition sources and safely stop flow of spill. Bund area. Trained personnel should wear Personal Protective equipment as highlighted in this MSDS. Blanket the spill with foam or use water fog to disperse vapour clouds. Consult an expert regarding disposal of this product.

7. HANDLING AND STORAGE	
Store in a cool place and out of direct sunlight.  Store away from sources of heat or ignition, alkalis, combustibles and oxidizing agents. All equipment must be earthed. Store in original packages as approved by manufacturer. Check all fittings, valves, reticulation (piping) and any ancillary equipment for leaks. A supplied air respirator or a Self-Contained Breathing Apparatus (SCBA) for emergencies should be available and checked regularly. For further information please refer to the Engineering Controls of this MSDS.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION	
Exposure Standards
 
No exposure standards are available for this product, however, the following exposure standards have been assigned by [NOHSC] to the following components of the product:

PHOSPHORIC ACID 
(Worksafe Australia)
[TWA]1 mg/m³
[STEL]3 mg/m³  

Engineering Controls
Corrosive liquid. Single significant exposure may cause severe injury or even death. Maintain adequate ventilation at all times. Prevent accumulation of vapours in hollows or sumps. Eliminate any sources of ignition. Exposure to this material may be controlled in a number of ways. The measures appropriate for a particular worksite depend on how the material is used and on the potential for exposure. Engineering methods to prevent or control exposure are preferred. Methods include process or personnel enclosure, mechanical ventilation (dilution and local exhaust), and control of process conditions. If engineering controls and work practices are not effective in preventing or controlling exposure, then suitable personal protective equipment, which is known to perform satisfactorily, should be used.

Personal Protection Equipment

This product is not corrosive or poisonous.  The following protective equipment is recommended in all circumstances when mixing or using this product in large volumes.
 
CLOTHING: PVC or Nitrile.
GLOVES: PVC or Nitrile.
EYES: Chemical goggles or face shield to protect eyes.
RESPIRATORY PROTECTION: Avoid breathing of vapours. Select and use respirators in accordance with AS/NZS 1715/1716. When the concentration of airborne contaminants reach the exposure standards then the use of a half-face respirator with acid vapour cartridge is recommended. For high concentration use a atmosphere-supplied, positive pressure demand self-contained or airline breathing apparatus supplied air respirator complying with the requirements of AS/NZS 1715 is recommended.  Filter capacity and respirator type depends on exposure levels and type of contaminant.
If entering spaces where the airborne concentration of a contaminant is unknown then the use of a Self-contained breathing apparatus (SCBA) with positive pressure air supply complying with AS/NZS 1715 / 1716, or any other acceptable International Standard is recommended.  The use of fully-encapsulating, gas-tight suit is also recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES	
Appearance: 	Viscous green liquid
Boiling Point Melting Point:	>100ºC
Vapour Pressure:	Not Known
Specific Gravity:	1.07
Flash Point:	None
Flammability Limits:	Non Flammable
Solubility in Water:	All proportions

Other Properties
pH (1% solution) :                             1.5 - 2.5
Odour :                                                 Pleasant pine frgrance

10. STABILITY AND REACTIVITY	
STABILITY:	Stable under normal conditions of use.

HAZARDOUS DECOMPOSITION PRODUCTS: Emits choking and corrosive fumes when heated to decomposition. 

HAZARDOUS POLYMERIZATION:	Will not occur.

INCOMPATIBILITIES: 	Strong bases, aluminium, zinc, magnesium and oxidizing agents. 

CONDITIONS TO AVOID: 	Heat and incompatibles. 

11. TOXICOLOGICAL INFORMATION	
No adverse health effects are expected, if the product is handled in accordance with this Material Safety Data Sheet and the product label. Symptoms and effects that may arise if the product is mishandled and overexposure occurs are:

ACUTE HEALTH EFFECTS:
Swallowed:
Will cause burns to the mouth, mucous membranes, throat, oesophagus and stomach. If sufficient quantities are ingested (swallowed) death may occur.

Eye: 
Will cause burns to the eyes with effects including: Pain, tearing, conjunctivitis and if duration of exposure is long enough, blindness will occur.

Skin:
Will cause burns to the skin, with effects including; Redness, blistering, localised pain and dermatitis.

Inhaled:
Will cause severe irritation to the nose, throat and respiratory system with effects including: Dizziness, headache, coughing, loss of co-ordination, chest pains, respiratory paralysis and or failure.

Chronic:
Prolonged or repeated skin contact will lead to necrosis of the skin.
Additional information for Chronic
Oral LD50(rat):1,530 mg/kg
Dermal LD50(rat): 2,740 mg/kg
Inhalation TCLo(Human): 100 mg/m3

Toxicological Data:
There is no other toxicological information available for this product. 

12. ECOLOGICAL INFORMATION	

Ecotoxity: 
This product will consume organic matter and is poisonous in aquatic environments in extremely large concentrations.

Mobility: 
Readily dilutes with water.

Persistence / Degradability:
Inherently Biodegradable.

Chemical Fate Information:
This substance may cause long term adverse effects in the aquatic environment.

13. DISPOSAL CONSIDERATIONS	
Refer to appropriate authority in your State. Dispose of material through a licensed waste contractor. Advise on acidic nature. Normally suitable for disposal by approved waste disposal agent.

14. TRANSPORT INFORMATION	
Road Transport
UN Number: None allocated
Proper Shipping Name:  None allocated
Dangerous Goods Class:  None allocated
Packing Group: None allocated
Label: None allocated

Air Transport
UN Number:None allocated
Proper Shipping Name: None allocated
Dangerous Goods Class: None allocated
Packing Group:  None allocated
Label: Corrosive none allocated
Sea Transport
UN Number: None allocated
Proper Shipping Name: None allocated 
Dangerous Goods Class: None allocated
Packing Group:  None allocated
Label: Corrosive none allocated

15. REGULATORY INFORMATION	
Poison Schedule: S5 [Aust]

Inventory Status:
Inventory                                               	Status
Australia (AICS)	All materials are listed.

16. OTHER INFORMATION	
Date of Preparation:

Issue date: 1/6/11
Supersedes: 1/3/10

Reasons for Update: 
New Format.

Key Legend Information:
NOHSC - National Occupational Health & Safety Commission {Formerly Worksafe}[Aust]
SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons [Aust]
TWA - Time Weighted Average [Int]
STEL - Short Term Exposure Limit [Int]
AICS - Australian Inventory of Chemical Substances
EPA - Environmental Protection Agency [Int]
NIOSH - National Institute for Occupational Safety and Health [US]
AS/NZS 1715 - Selection, use and maintenance of respiratory protective devices. [Aust/NZ]
AS/NZS 1716 - Respiratory protective devices. [Aust/NZ]
IATA - International Aviation Transport Authority [Int]
ICAO - International Civil Aviation Organization [Int]
IMO - International Maritime Organisation. [Int]
IMDG - International Maritime Dangerous Goods [Int]
United Nations Recommendations for the Transport of Dangerous Goods and Globally Harmonized System for the classification and labelling of Chemicals. [Int]
EU - European Union

[Aust/NZ] = Australian New Zealand
[Int] = International
[US] = United States of America

Removal of the heading of Poison Schedule [Aust], in section 3 and 15 of this Material Safety Data Sheet (MSDS) makes this a valid health and safety document in other international jurisdictions/countries. For full compliance please contact your Federal, State or Local regulators for further information.

Disclaimer
This MSDS summarises our best knowledge of the health and safety hazard information available on the product and the measures to be used to handle and use the product safely. Each user should read this MSDS and consider the information in connection with the way the product is intended to be handled or used.

Principal References:
Information supplied by manufacturer, reference sources including the public domain.

END OF MSDS